US patent 5505799 looks like manual for 9/11 "explosive"

Two weeks ago a german fellow found this patent by accident in search for an online discussion with so called debunkers, originally by searching the temperature of thermite burning.
US patent 5505799: called, Nanoengineered Explosives, Filed 1993, granted 1996,

http://patft.uspto.gov/netacgi/nph-Parser?Sect1=PTO1&Sect2=HITOFF&d=PALL&p=1&u=%2Fnetahtml%2FPTO%2Fsrchnum.htm&r=1&f=G&l=5...

I forwarded this patent to Prof. Harrit who did immediately respond and called it a good catch, and begged me I should write a blog entry about it. Also, Prof. Jones did respond immediately, too, with the multilayers working on his mind. Because this patent describes a three-layered “near” explosive material.

This patent looks like the manual for what was found in the WTC dust. Maybe the biggest hint is the last figure (31) published in the work “Actice Thermitic Material Discovered In Dust Of The World Trade Center Catastrophe” by Niels Harrit et al,
http://www.benthamscience.com/open/tocpj/articles/V002/7TOCPJ.htm
showing a residue with two red-grey-layers and other layers as well.

There are several sentences you have to read from the patent:

“A complex modulated structure of reactive elements that have the capability of considerably more heat than organic explosives while generating a working fluid or gas. The explosive and method of fabricating same involves a plurality of very thin, stacked, multilayer structures, each composed of reactive components, such as aluminum, separated from a less reactive element, such as copper oxide, by a separator material, such as carbon. The separator material not only separates the reactive materials, but it reacts therewith when detonated to generate higher temperatures. The various layers of material, thickness of 10 to 10,000 angstroms, can be deposited by magnetron sputter deposition. The explosive detonates and combusts a high velocity generating a gas, such as CO, and high temperatures”

“The reaction of metals (i.e. Al, Ti, Be . . . ) with inorganic oxides (i.e. CuO, Fe.sub.2 O.sub.3, MnO.sub.2 . . . ) is well known. For example, the reaction of Al and Fe.sub.2 O.sub.3 to produce Al.sub.2 O.sub.3 and Fe is referred to as the Thermite reaction, and it has been used for many years in metallurgical processes, such as welding.
Also, the enhanced reactivity of thin multilayer structures compared to powder mixtures has been observed by other researchers. The reactivity of thin multilayer structures is attributed to the energy stored in the layer interfaces and the very high ratio of interface area to volume.”

“Unlike organic explosive molecules, this explosive has properties that can be engineered because the structure is a fabricated multilayer not determined by molecular structure and bonding. It provides an alternative to any application for organic propellants or explosives. The stability of inorganic materials from which the new type explosive consists make it attractive for use in severe environments such a space applications. Also, the multilayer structure can be engineered to provide desired ignition temperatures and detonation characteristics. For example, the multilayer explosive can be engineered to be ignited by a mechanical scratch at room temperature, or to be as insensitive to ignition as a mixture of powder components. In addition, the ability to control the thickness (from 10 to 10,000 angstroms) of the various layers in the multilayer structure provide control over ignition sensitivity. Thicker layers in the multilayer structure produce a more stable material. In addition to beryllium, aluminum, and titanium, other inorganic elements or reactive metals such as lithium (Li), calcium (Ca), zirconium (Zr), and yttrium (Y), may be used. Also, the inorganic oxides of other metals, such as gallium (Ga), zinc (Zn), nickle (Ni), cobalt (Co), molybdenium (Mo), tin (Sn), and germanium (Ge) may be used. While carbon is the preferred organic component layer between the reactive layer and the oxide layer, other organic components (i.e. polymer films) which will react with both but also prevents any passivating reaction between the reactive material and the inorganic oxide material, may be used.”

I would call it only a manual, with strong evidence such material could in fact be developed long before 9/11, because, sure, there are at least the following differences:
-In the patent CuO (cupper-oxide) was used for the metal-oxide. In the red-grey chips described by Harrit et al they found FeO. However, FeO (iron oxide) is mentioned in the patent as the metal-oxide for well known thermite reaction (see above). What are the differences: CuO is faster in the reaction, but more expensive, too, as cupper is much more expensive than iron. There is no doubt that FeO can be used, too, with a little slower reaction front.
-there are three distinguishable layers, each useful for a special purpose, described in the patent: The CuO for the metal-oxide, the carbon layer for secure handling and creating carbide in the reaction and the Al-layer delivering the aluminum for the reaction. In the red-layer of the red-grey chip it looks like more than one of the features of the patents different layers were used, aka Al, FeO and C together. As there is the possibility, that more layers were used and only fragments of the layers were found, or that for other purposes the layers were even intermixed, it is no reason to undermine the meaning of this patent.
-magnetron sputtering is not a likely method for creating the amounts of nano-engineered explosives eventually used for the WTC destruction
-the term "explosive" shoud be used with caution, as there are clear definitions of it- we have a new stuff here, on the border between beeing explosive and incendiary

So, besides this, we can put a few things to rest: A stuff combining best of two worlds, as described later in science, a reaction speed likewise of explosives with the potential energy of incendiaries, nanomaterial layers capable of producing gas, carbides, very high temperatures in the reaction, like explosives, features adjustable just what you want from it, because of the adjustable layer features, known as early as 1993…means: Such stuff is possible. Don’t matter how often the “debunkers” will say thermite is not an explosive and the layers were much too thin for any harming of WTC steel. This looks like an important further step for reaching out to the criminals who did blow up the towers.

This patent can be found only randomly, if ever, in regards to 9/11 truth, e.g. you will find some comments on the web by harrasing "debunker" "Merlin5by5" on youtube or a short article by 911truth.ch. However, this information can be considered new to a wider audience, including the authors of the "Active Thermictic Material..." Even if it is not exactly the stuff that was used in the WTC demolition, hopefully it is a useful contribution for further studies.

"Also....

...the multilayer structure can be engineered to provide desired ignition temperatures and detonation characteristics. For example, the multilayer explosive can be engineered to be ignited by a mechanical scratch at room temperature, or to be as insensitive to ignition...."

Perhaps this a clue to the answer to often asked question..." why didn't the airplane fireball ignite the nanothermite?"

Our Figures 31,32 in the Active Thermitic Materials paper show

multiple layers, and Fig. 33 shows the composition of the "light gray" layer. Thus, both Fig 32 AND Fig 31 show the multiple layers. We published these results, and any future study of the WTC dust should also look for these multiple-layered red-gray chips.

It is very interesting that this 1996 (pre-9/11/01) patent specifies that a thermitic reaction can be explosive, and that it can be tailored as Jon Cole noted above. Further, the patent notes:

“The reaction of metals (i.e. Al, Ti, Be . . . ) with inorganic oxides (i.e. CuO, Fe.sub.2 O.sub.3, MnO.sub.2 . . . ) is well known. For example, the reaction of Al and Fe.sub.2 O.sub.3 to produce Al.sub.2 O.sub.3 and Fe is referred to as the Thermite reaction, and it has been used for many years in metallurgical processes, such as welding. Also, the enhanced reactivity of thin multilayer structures compared to powder mixtures has been observed by other researchers. The reactivity of thin multilayer structures is attributed to the energy stored in the layer interfaces and the very high ratio of interface area to volume."

Thus, multi-layering results in "enhanced reactivity". Not surprising.

As shown in our published Figure 33 in our paper, the light gray layer contains Carbon and Oxygen and possibly Hydrogen; hydrogen is too light an element to be seen with the XEDS system. There is no iron in this layer as we noted in the paper.
When writing the paper, I opined that this light-gray layer is a hydrocarbon, present to provide gas-pressure on ignition of the red material. However, I grant that this gray layer may be primarily carbon with some oxidation present; as the 1996 patent points to [quote]" a separator material, such as carbon. The separator material not only separates the reactive materials, but it reacts therewith when detonated to generate higher temperatures."

It is difficult to see how a "paint" applied to steel could result in such multiple-layered chips as we observed in the WTC dust. Have debunkers even attempted to account for the multiple-layered chips which we reported finding in the WTC dust?

--> Any other study of the red-gray chips which fails to replicate our finding of multiple-layered red-gray chips is seen to be INCOMPLETE at best.

Bravo

This is a FIND.

Another patent

Energetic composites
US 5266132 A

http://www.google.de/patents/US5266132

1993, Department of Energy (Contract No. W-7405-ENG-36).

Highlights:

In addition to MICs which can be designed such that the reactions proceed rapidly, MICs which react more slowly can be designed. In general, MICs can be designed to suit the application. For example, if the application requires heat but not gasses, the MIC can be so designed.

The temperature of MICs during reaction has been measured and found to be as high as 6000 K (= 5726° Celsius)

The Table shows materials which are expected to be useful as reactive substances for MICs and the products of the reactions. The list of materials is not intended to be all-inclusive, but is simply a selection of potential reactions.

Fe.sub.2 O.sub.3 + 2 Al → Al.sub.2 O.sub.3 + 2 Fe -1.0

The type of energy release can be varied according to the application; for example, it may be only thermal or may be thermal with release of large quantities of gas. In addition to weapons and explosives applications, MICs will be useful in welding, forming, and heating metals and serving as a heat source where very high temperatures are required or where lower temperatures are needed for a period of time.

Ignition studies of Al/Fe2O3 energetic nanocomposites

Fasten seat belts.

Although this single layered nanorod thermitic MIC is not exactly the same as found by Harrit et al, look at the numbers!

"Ignition is accompanied by a bright flash of light. The reaction temperature is obtained by measuring the blackbody emission spectrum of the igniting sample. Figure 5 shows the plot of flame temperature as a function of ignition temperature. Ignition starts at a temperature of ;410 °C.
As expected, the flame temperature is independent of the ignition temperature and is of the order of 4000 °C. The high flame temperature is consistent with the large energy release expected."

http://www.depts.ttu.edu/ntc/ResearchAndPublications/Publications/pdf/2004/APL_Fe_nanowires_2004.pdf

Nanothermite

I've been thinking about this and it seems clear that thermitic charges make perfect sense as a 'pre-weakener' for a deceptive demolition as it keeps the noise levels to a minimum. Once the demolition process starts there's enough background noise to use more conventional charges. And it would explain the "molten metal" seen pouring from the South Tower prior to its total collapse.

I doubt this thought is new with me, but it should be kept in mind when 'debunkers' use the "demolition experts would never use thermite" canard.